| Jornada 1 | 26-08-2001 | RAYO VALLEC. | 1 | VILLARREAL | 2 |
| Jornada 2 | 09-09-2001 | FC BARCELONA | 1 | RAYO VALLEC. | 1 |
| Jornada 3 | 16-09-2001 | RAYO VALLEC. | 1 | ZARAGOZA | 2 |
| Jornada 4 | 23-09-2001 | SEVILLA | 2 | RAYO VALLEC. | 1 |
| Jornada 5 | 30-09-2001 | ESPANYOL | 3 | RAYO VALLEC. | 1 |
| Jornada 6 | 03-10-2001 | RAYO VALLEC. | 0 | OSASUNA | 1 |
| Jornada 7 | 07-10-2001 | TENERIFE | 3 | RAYO VALLEC. | 1 |
| Jornada 8 | 14-10-2001 | RAYO VALLEC. | 2 | REAL SOCIEDAD | 1 |
| Jornada 9 | 21-10-2001 | MALLORCA | 3 | RAYO VALLEC. | 0 |
| Jornada 10 | 28-10-2001 | RAYO VALLEC. | 2 | DEPORTIVO | 1 |
| Jornada 11 | 04-11-2001 | VALENCIA | 2 | RAYO VALLEC. | 1 |
| Jornada 12 | 11-11-2001 | RAYO VALLEC. | 3 | MALAGA | 0 |
| Jornada 13 | 18-11-2001 | BETIS | 2 | RAYO VALLEC. | 0 |
| Jornada 14 | 25-11-2001 | RAYO VALLEC. | 0 | REAL MADRID | 3 |
| Jornada 15 | 02-12-2001 | VALLADOLID | 3 | RAYO VALLEC. | 1 |
| Jornada 16 | 09-12-2001 | RAYO VALLEC. | 0 | LAS PALMAS | 0 |
| Jornada 17 | 16-12-2001 | ATHLETIC BILBAO | 1 | RAYO VALLEC. | 1 |
| Jornada 18 | 23-12-2001 | RAYO VALLEC. | 2 | ALAVES | 0 |
| Jornada 19 | 06-01-2002 | CELTA | 2 | RAYO VALLEC. | 2 |
| Jornada 20 | 13-01-2002 | VILLARREAL | 1 | RAYO VALLEC. | 1 |
| Jornada 21 | 20-01-2002 | RAYO VALLEC. | 2 | FC BARCELONA | 1 |
| Jornada 22 | 27-01-2002 | ZARAGOZA | 3 | RAYO VALLEC. | 2 |
| Jornada 23 | 03-02-2002 | RAYO VALLEC. | 2 | SEVILLA | 1 |
| Jornada 24 | 06-02-2002 | RAYO VALLEC. | 2 | ESPANYOL | 2 |
| Jornada 25 | 10-02-2002 | OSASUNA | 1 | RAYO VALLEC. | 0 |
| Jornada 26 | 17-02-2002 | RAYO VALLEC. | 2 | TENERIFE | 0 |
| Jornada 27 | 24-02-2002 | REAL SOCIEDAD | 2 | RAYO VALLEC. | 2 |
| Jornada 28 | 03-03-2002 | RAYO VALLEC. | 0 | MALLORCA | 2 |
| Jornada 29 | 10-03-2002 | DEPORTIVO | 1 | RAYO VALLEC. | 1 |
| Jornada 30 | 17-03-2002 | RAYO VALLEC. | 2 | VALENCIA | 1 |
| Jornada 31 | 24-03-2002 | MALAGA | 0 | RAYO VALLEC. | 0 |
| Jornada 32 | 31-03-2002 | RAYO VALLEC. | 0 | BETIS | 0 |
| Jornada 33 | 07-04-2002 | REAL MADRID | 3 | RAYO VALLEC. | 1 |
| Jornada 34 | 14-04-2002 | RAYO VALLEC. | 1 | VALLADOLID | 0 |
| Jornada 35 | 21-04-2002 | LAS PALMAS | 0 | RAYO VALLEC. | 2 |
| Jornada 36 | 28-04-2002 | RAYO VALLEC. | 4 | ATHLETIC BILBAO | 2 |
| Jornada 37 | 05-05-2002 | ALAVES | 0 | RAYO VALLEC. | 1 |
| Jornada 38 | 12-05-2002 | RAYO VALLEC. | 1 | CELTA | 0 |